Polarographic Study of Potassium Ethyl Xanthate

Electrochemical study of potassium isobutyl xanthate at a mercury electrode.

Polarographic studies of potassium isobutyl xanthate at a mercury electrode reveal that the product of an anodic reaction is strongly adsorbed at the mercury surface, as indicated by a prewave. The adsorbed film greatly affects the characteristics of the anodic wave of xanthate in an aqeous medium. The current of total wave is proportional to the concentration of xanthate from 0.32 to 1.6 mM.

Substoichiometric radiochemical determination of silver with potassium ethyl xanthate in photofilm washings.

An accurate and rapid radiochemical method has been developed for the determination of microgram amount of silver employing potassium ethyl xanthate as a substoichiometric radiochemical reagent. The light yellow coloured silver ethyl xanthate formed was extracted into nitrobenzene from sulphuric acid media. The effect of foreign ions on the extraction was studied. The method was applied to the ...

Direct Force Measurement between Hydrophobic Glass Sphere and Covellite Electrode in Potassium Ethyl Xanthate Solutions at pH 9.2

Froth flotation is the most widely used method of separating minerals from one another. The basis of this process is to control the hydrophobicity of the minerals to be separated. The most commonly used measure of hydrophobicity is the water contact angle (θ), which is usually measured on polished mineral surfaces using either sessile drop or captive bubble technique. However, contact angle is ...

Electrochemistry of Copper Activation of Sphalerite and Potassium Isobutyl Xanthate (KIBX) Synthesized Collectors Adsorption

POLAROGRAPHIC AND POTENTIOSTATIC REDUCTION OF CARBODIIMIDES: A MECHANISTIC STUDY

The polarographic reduction of aromatic carbodiimides in anhydrous aprotic solvents goes through a carbene intermediate by a diffusion controlled process in two one-electron steps. The first step is the rate-determining step and converts the carbodiirnide to a radical anion (6) that reduces further by a fast one-electron step to a carbene dianion intermediate (7). This abstracts an oxygen, ...